Donor mode of NO ligand depends on the metal. Now, consider the following complexes (in gaseous state). (A)… · ABC26IN0146
Subject: Inorganic Chemistry · Chapter: Coordination Chemistry · Topic: Molecular Orbital Ligand Field · Exam: CSIR NET 2019 · Marks: 2 · Difficulty: Medium
Donor mode of NO ligand depends on the metal. Now, consider the following complexes (in gaseous state). (A) $\mathrm{[IrCl(CO)(PPh_3)_2(NO)]^+}$ (B) $\mathrm{[RuCl(PPh_3)_2(NO)_2]^+}$ (C) $\mathrm{[Co(NCS)(diars)_2(NO)]^+}$, where diars $\rightarrow$ o-$\mathrm{(Me_2As)_2C_6H_4}$. (D) $\mathrm{[Cr(CN)_5(NO)]^{3-}}$ The complex(es) that do NOT exhibit bent NO coordination mode is/are [CSIR-JUNE 2019]