ABC26IN0151 · Coordination Chemistry

Subject: Inorganic Chemistry · Chapter: Coordination Chemistry · Topic: Electron Transfer Redox · Exam: CSIR-NET 2020 · Marks: 2 · Difficulty: Medium

In the electronic spectrum of $[\mathrm{IrBr_6}]^{2-}$, the number of charge transfer band(s) and their origin are respectively
(a)Two ligand $\rightarrow$ metal ($\sigma \rightarrow \mathrm{t_{2g}}$ and $\sigma \rightarrow \mathrm{a_{1g}}^{*}$)
(b)One ligand $\rightarrow$ metal ($\sigma \rightarrow \mathrm{e_g}$)
(c)Two ligand $\rightarrow$ metal ($\sigma \rightarrow \mathrm{t_{2g}}$ and $\sigma \rightarrow \mathrm{e_g}$ )
(d)One ligand $\rightarrow$ metal ($\sigma \rightarrow \mathrm{t_{2g}}$)
Answer
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Explanation
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