ABC26IN0251 · Organometallic Compounds

Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Cluster Compounds Wade Rules · Exam: CSIR-NET 2015 · Marks: 2 · Difficulty: Easy

According to Wade's theory the anion $\left[\mathrm{B}_{12} \mathrm{H}_{12}\right]^{2-}$ adopts
(a)closo-structure
(b)arachno-structure
(c)hypo-structure
(d)nido-structure
Answer
Answer (as printed): A
Explanation
$[\mathrm{B_{12}H_{12}}]^{2-} \equiv [\mathrm{B_nH_n}]^{2-}$ Therefore, it is closo structure

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