For an inverse spinel, AB₂O₄, the A and B, respectively, can be · ABC26IN0395

Subject: Inorganic Chemistry · Chapter: Coordination Chemistry · Topic: Coordination – General · Exam: GATE 2005-2021 · Marks: 2 · Difficulty: Easy

For an inverse spinel, $\mathrm{AB_2O_4}$, the A and B, respectively, can be
(a)Ni(II) and Ga(III)
(b)Zn(II) and Fe(III)
(c)Fe(II) and Cr(III)
(d)Mn(II) and Mn(III)
Answer
Answer: A ✓ checked by 4AB · confidence high
Explanation
NiGa₂O₄ is inverse: Ni²⁺ (d⁸, strong octahedral preference) takes octahedral sites, Ga³⁺ (d¹⁰) splits between sites (a).

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