[Co(CO)₄] is isolobal with · ABC26IN0490

Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Organometallic Compounds – General · Exam: GATE 2005-2021 · Marks: 2 · Difficulty: Easy

$\left[\mathrm{Co}(\mathrm{CO})_{4}\right]$ is isolobal with
(a)$\mathrm{CH}_{4}$
(b)$\mathrm{CH}_{3}$
(c)$\mathrm{CH}_{2}$
(d)CH
Answer
Answer: B ✓ checked by 4AB · confidence high
Explanation
[Co(CO)₄]• is a 17-electron d⁹ ML₄ fragment with one frontier orbital holding one electron, isolobal with the methyl radical CH₃• (e.g. Co₂(CO)₈ ↔ ethane, HCo(CO)₄ ↔ methane).

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