ABC26IN1041 · Coordination Chemistry

Subject: Inorganic Chemistry · Chapter: Coordination Chemistry · Topic: Electron Transfer Redox · Exam: NET JUNE 2014 · Marks: 2 · Difficulty: Medium

In its electronic spectrum, $\left[\mathrm{V}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{3+}$ exihibits two absorption bands, one at 17,800 ($v_1$) and the second at 25, 700 ($v_2$) cm. The correct assignment of these bands, respectively, is
(a)$v_1 = {}^3T_{1g}(F) \rightarrow {}^3T_{2g}(F)$, $V_2 = {}^3T_{1g}(F) \rightarrow {}^3T_{1g}(P)$
(b)$v_1 = {}^3T_{1g}(F) \rightarrow {}^3T_{1g}(P)$, $V_2 = {}^3T_{1g}(F) \rightarrow {}^3T_{2g}(P)$
(c)$v_1 = {}^3A_{2g} \rightarrow {}^3T_{1g}(F)$, $V_2 = {}^3A_{2g} \rightarrow {}^3T_{2g}(F)$
(d)$v_1 = {}^3A_{2g} \rightarrow {}^3T_{2g}(F)$, $V_2 = {}^3A_{2g} \rightarrow {}^3T_{1g}($ (F)
Answer
Answer (as printed): A
Explanation
No explanation was printed for this question.

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