ABC26IN1351 · Organometallic Compounds

Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Cluster Compounds Wade Rules · Exam: NET DEC 2011 · Marks: 2 · Difficulty: Medium

Reaction of $\mathrm{Fe}(\mathrm{CO})_{5}$ with OH leads to complex A which on oxidation with $\mathrm{MnO}_{2}$ gives B . Compounds A and B respectively are
(a)$\left[\mathrm{HFe}(\mathrm{CO})_{4}\right]^{-}$and $\mathrm{Fe}_{3}(\mathrm{CO})_{12}$
(b)$\left[\mathrm{Fe}(\mathrm{CO})_{5}(\mathrm{OH})\right]^{-}$and $\mathrm{Fe}_{2}(\mathrm{CO})_{10}$
(c)$\left[\mathrm{Fe(CO)_4}\right]^{2-}$ and $\mathrm{Mn_2(CO)_{10}}$
(d)$\left[\mathrm{HFe}(\mathrm{CO})_{4}\right]^{-}$, and $\mathrm{Fe}_{2} \mathrm{O}_{3}$
Answer
Answer (as printed): A
Explanation
No explanation was printed for this question.

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