The reaction, [(CO)₅ Mn(Me)]+CO → [(CO)₅ Mn{C(O) Me}] is an example for · ABC26IN1375

Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Oxidative Addition Reductive Elimination · Exam: CSIR NET JUNE 2013 · Marks: 2 · Difficulty: Easy

The reaction, $\left[(\mathrm{CO})_{5} \mathrm{Mn}(\mathrm{Me})\right]+\mathrm{CO} \rightarrow\left[(\mathrm{CO})_{5} \mathrm{Mn}\{\mathrm{C}(\mathrm{O}) \mathrm{Me}\}\right]$ is an example for
(a)oxidative addition
(b)electrophilic substitution
(c)nucleophilic substitution
(d)migratory insertion
Answer
Answer: D ✓ checked by 4AB · confidence high
Explanation
The methyl group migrates onto an adjacent coordinated CO to give the acetyl ligand; the vacant site is then filled by external CO — CO migratory insertion.

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