ABC26OR0124 · Organic Spectroscopy

Subject: Organic Chemistry · Chapter: Organic Spectroscopy · Topic: UV Vis · Exam: CSIR-NET JUNE 2013 · Marks: 2 · Difficulty: Medium

In the UV-visible is spectrum, a diterpenoid exhibited a $\lambda_{\max }=275 \mathrm{nm}$. The compound, among the choices given below is
(a)structure
(b)structure
(c)structure
(d)structure
Answer
Answer (as printed): C
Explanation
For Homo annular diene, Basic value = 253 Ring residue = 20 Exo double bond = 5 That adds up to: 253 + 20 + 5 = 278 nm. This value is close to 275 nm. Thus, correct answer is (c).

Explanation as extracted from the printed page; notation may be imperfect.

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