Among the following compounds, the one that is non-aromatic, is · ABC26OR0750

Subject: Organic Chemistry · Chapter: Stereochemistry · Topic: Stereochemistry – General · Exam: GATE 2000-2022 · Marks: 2 · Difficulty: Easy

Among the following compounds, the one that is non-aromatic, is
(a)Option (a) structure, ABC26OR0750
(b)Option (b) structure, ABC26OR0750
(c)Option (c) structure, ABC26OR0750
(d)Option (d) structure, ABC26OR0750
Answer
Answer: A ✓ checked by 4AB · confidence high
Explanation
(a) Cyclooctatetraene (8π) is not planar. It adopts a tub shape, so it is non-aromatic.
(b) Benzyne keeps the aromatic 6π sextet; its extra π bond lies in the ring plane, so it is aromatic. (c) Cyclobutadiene (4π, planar) is antiaromatic. (d) 1,6-Methano[10]annulene (10π) is aromatic.
The non-aromatic compound is cyclooctatetraene, option (a).

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