ABC26PH0118 · Molecular Spectroscopy

Subject: Physical Chemistry · Chapter: Molecular Spectroscopy · Topic: Rotational · Exam: CSIR-NET JUNE 2019 · Marks: 2 · Difficulty: Medium

The Berge-Sponer plot between $\Delta G_{v+\frac{1}{2}}=(\varepsilon_{v+1}-\varepsilon_{v})$ and $(v+1)$ for CO ia a straight line with slope of $-14\,\mathrm{cm^{-1}}$ and intercept of $2170\,\mathrm{cm^{-1}}$. The approximate value of dissociation energy of CO (in $\mathrm{cm^{-1}}$) is (Assume CO as an Anharmonic oscillator with energy expression.
\[ \varepsilon_v=\left(v+\frac{1}{2}\right)\omega-\left(v+\frac{1}{2}\right)^{2}x_e\omega; \quad D=\frac{\omega}{4x_e} \]
(a)42044
(b)84088
(c)168175
(d)336350
Answer
Answer (as printed): C
Explanation
No explanation was printed for this question.

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