In a molecule XY, let ψX and ψY denote normalized atomic orbitals of atoms X and Y, respectively. A… · ABC26PH0322

Subject: Physical Chemistry · Chapter: Atomic Structure · Topic: Atomic Structure – General · Exam: GATE 2005-2021 · Marks: 2 · Difficulty: Medium

In a molecule XY, let $\psi_X$ and $\psi_Y$ denote normalized atomic orbitals of atoms X and Y, respectively. A normalized molecular orbital of XY is given by $\psi_+ = 0.56(\psi_X + \psi_Y)$. The value of the overlap integral of $\psi_X$ and $\psi_Y$ is ____ (Upto two decimal place)
Answer
SELF-PRACTICE — the source book printed no answer.

Nothing is invented here, so this question has no answer on record.

Explanation
Answer: 0.59 — 0.56²(2 + 2S) = 1 gives 2 + 2S = 3.189, so S = 0.59.

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