ABC26PH0397 · Electrochemistry

Subject: Physical Chemistry · Chapter: Electrochemistry · Topic: Nernst Cells · Exam: GATE 2005-2021 · Marks: 2 · Difficulty: Medium

At 298 K, the EMF of the cell
\[ \mathrm{pt} \mid \mathrm{H}_{2}(1\,\mathrm{bar}) \mid \mathrm{H}^{+}(\text{solution}) \| \mathrm{Cl}^{-} \mid \mathrm{Hg_2Cl_2}\mathrm{Hg} \]
is 0.7530 V. The standard potential of the calomel electrode is 0.2802 V. If the liquid junction potential is zero, the pH of the solution is:
(a)4.7
(b)7.4
(c)8.0
(d)12.7
Answer
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Explanation
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