For the reaction, Q + R k₋₁k₁⇌ X k₂ P k₁ = 2.5 × 10⁵ L mol⁻¹ s⁻¹, k₋₁ = 1.0 × 10⁴ s⁻¹ and k₂ = 10 s⁻¹. Under… · ABC26PH0653

Subject: Physical Chemistry · Chapter: Chemical Kinetics · Topic: Chemical Kinetics – General · Exam: JAM 2001-2022 · Marks: 2 · Difficulty: Medium

For the reaction,
$$\mathrm{Q + R \underset{k_{-1}}{\stackrel{k_1}{\rightleftharpoons}} X \xrightarrow{k_2} P}$$
$k_1 = 2.5 \times 10^5\,\mathrm{L\,mol^{-1}\,s^{-1}}$, $k_{-1} = 1.0 \times 10^4\,\mathrm{s^{-1}}$ and $k_2 = 10\,\mathrm{s^{-1}}$. Under steady state approximation, the rate constant for the overall reaction in $\mathrm{L\,mol^{-1}\,s^{-1}}$ (rounded off to the nearest integer) is ____.
Answer
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