ABC26PH0840 · Thermodynamics and Thermochemistry

Subject: Physical Chemistry · Chapter: Thermodynamics and Thermochemistry · Topic: Thermodynamics & Thermochemistry – General · Exam: JAM 2001-2022 · Marks: 2 · Difficulty: Easy

15(a) One mole of an ideal gas initially at 300 K and at a pressure of 10 atm undergoes adiabatic expansion. (i) Reversibly and (ii) Irreversibly against a constant external pressure of 2 atm until the final pressure becomes equal to the external pressure. Calculate $\Delta \mathrm{S}_{\text {system }}$ for (i) and (ii). For (ii), express the final answer in terms of R. Given: Molar heat capacity at constant volume $\mathrm{C}_{\mathrm{v}, \mathrm{m}}=3 \mathrm{R} / 2$.
Answer
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Explanation
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