ABC26PH1251 · Quantum Chemistry

Subject: Physical Chemistry · Chapter: Quantum Chemistry · Topic: Postulates Operators · Exam: NET JUNE 2014 · Marks: 2 · Difficulty: Medium

The ground state energy of hydrogen atom is -13.598 eV . The expectation values of kinetic energy, $<\mathrm{T}>$ and potential energy, <V>, in units of eV, are
(a)$\langle\mathrm{T}\rangle=13.598,\langle\mathrm{V}\rangle=-27.196$
(b)$\langle\mathrm{T}\rangle=-27.196,\langle\mathrm{V}\rangle=13.598$
(c)$\langle\mathrm{T}\rangle=-6.799,\langle\mathrm{V}\rangle=-6.799$
(d)$\langle\mathrm{T}\rangle=6.799,\langle\mathrm{V}\rangle=-20.397$
Answer
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