The correct statement about base hydrolysis of [Co(py)₄Cl₂]⁺ (py-pyridine) is · ABC26IN0148

Subject: Inorganic Chemistry · Chapter: Coordination Chemistry · Topic: Reaction Mechanisms Substitution · Exam: CSIR NET 2019 · Marks: 2 · Difficulty: Medium

The correct statement about base hydrolysis of $[\mathrm{Co(py)_4Cl_2}]^{+}$ (py-pyridine) is
(a)rate expression is, Rate-$\mathrm{k}[\mathrm{Co(py)_4Cl_2}]^{+}[\mathrm{OH^{-}}]$
(b)reaction does not depend on hydroxide ion concentration
(c)reaction proceeds through $\mathrm{S_{N1}CB}$ mechanism
(d)intermediate involved in this reaction is $[\mathrm{Co(py)_4Cl_2(OH)}]$
Answer
Answer: B ✓ checked by 4AB · confidence high
Explanation
Pyridine has no N–H, so no conjugate base can form and the S_N1CB pathway is closed; base hydrolysis of [Co(py)₄Cl₂]⁺ is therefore slow and independent of [OH⁻] — statement (2).

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