The homolytic breaking of the Ca-Cb bond is easiest in: · ABC26OR0783

Subject: Organic Chemistry · Chapter: General Organic Chemistry · Topic: General Organic Chemistry – General · Exam: JAM 2005-2022 · Marks: 2 · Difficulty: Easy

The homolytic breaking of the $\mathrm{C}_{\mathrm{a}}-\mathrm{C}_{\mathrm{b}}$ bond is easiest in:
(a)Option (a) structure, ABC26OR0783
(b)Option (b) structure, ABC26OR0783
(c)Option (c) structure, ABC26OR0783
(d)Option (d) structure, ABC26OR0783
Answer
Answer: D ✓ checked by 4AB · confidence high
Explanation
Homolysis gives two tertiary radicals in 2,2,3,3-tetramethylbutane, and relieves severe steric strain — weakest Ca–Cb bond (d).

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