Simple Hückel molecular orbital theory · ABC26PH0154

Subject: Physical Chemistry · Chapter: Quantum Chemistry · Topic: Huckel MO Theory · Exam: CSIR NET 2014 · Marks: 2 · Difficulty: Easy

Simple Hückel molecular orbital theory
(a)considers electron-electron repulsion explicitly
(b)distinguishes cis-butadiene and trans butadiene
(c)distinguishes cyclobutadiene cis-butadiene
(d)has different coulomb integrals for non equivalent carbons
Answer
Answer: C ✓ checked by 4AB · confidence high
Explanation
Simple Hückel theory uses only connectivity: it ignores electron repulsion, gives every carbon the same α, and cannot tell cis- from trans-butadiene. It does distinguish cyclobutadiene from butadiene because the ring has an extra C–C bond (different secular determinant).

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