Adsorption of N₂ on TiO₂ was carried out at 75 K. A plot of z/((1-z)V) versus z (z = p/p⁰) gives a straight… · ABC26PH0485

Subject: Physical Chemistry · Chapter: Surface Chemistry · Topic: Surface Chemistry – General · Exam: GATE 2005-2021 · Marks: 2 · Difficulty: Medium

Adsorption of $\mathrm{N_2}$ on $\mathrm{TiO_2}$ was carried out at 75 K. A plot of $\frac{z}{(1-z)V}$ versus $z$ ($z = p/p^0$) gives a straight line with an intercept, $4.0 \times 10^{-6}\ \mathrm{mm^{-3}}$ and slope, $1.0 \times 10^{-3}\ \mathrm{mm^{-3}}$. The volume (rounded off to the nearest integer) corresponding to the monolayer coverage is:
(a)$555\ \mathrm{mm^3}$
(b)$690\ \mathrm{mm^3}$
(c)$785\ \mathrm{mm^3}$
(d)$996\ \mathrm{mm^3}$
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