Q94 · CSIR NET Chemistry, December 2011

Paper: CSIR NET December 2011 · Subject: Physical Chemistry · Chapter: Electrochemistry · Topic: Conductance · Marks: 2 · Difficulty: Medium

The overall reaction for the passage of 1.0 faraday of charge in the following cell $\mathrm{Ag(s)-AgCl(s)\,|\,KCl(a_1)\,|\,KCl(a_2)\,|\,AgCl(s)-Ag(s)}$ is given by (t denotes the transport numbers)
(a)$t_+\,\mathrm{KCl(a_1)} \rightarrow t_+\,\mathrm{KCl(a_2)}$
(b)$t_+\,\mathrm{KCl(a_2)} \rightarrow t_+\,\mathrm{KCl(a_1)}$
(c)$t_-\,\mathrm{KCl(a_1)} \rightarrow t_-\,\mathrm{KCl(a_2)}$
(d)$t_-\,\mathrm{KCl(a_2)} \rightarrow t_-\,\mathrm{KCl(a_1)}$
Answer
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Explanation
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