Q81 · CSIR NET Chemistry, December 2016

Paper: CSIR NET December 2016 · Subject: Physical Chemistry · Chapter: Chemical Kinetics · Topic: Rate Laws Order · Marks: 2 · Difficulty: Medium

The rate of an acid-catalyzed reaction in aqueous solution follows the rate equation
$r = k[\mathrm{X^+}][\mathrm{Y^{2-}}][\mathrm{H^+}]$
If $k_{16}$ and $k_4$ are rate constants for the reaction at ionic strength of $16\ \mathrm{mol\,L^{-1}}$ and $4\ \mathrm{mol\,L^{-1}}$, respectively $\ln\frac{k_4}{k_{16}}$, in terms of Debye-Huckel constant $(B = 0.51)$, is
(a)4B
(b)8B
(c)10B
(d)12B
Answer
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Explanation
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