Q66 · CSIR NET Chemistry, June 2013

Paper: CSIR NET June 2013 · Subject: Organic Chemistry · Chapter: Organic Spectroscopy · Topic: Organic Spectroscopy – General · Marks: 2 · Difficulty: Medium

In the broad band decoupled $^{13}\mathrm{C NMR}$ spectrum, the number of signals appearing for the two pyrene diols A and B Question structure 1 of 2, ABC26OR0959 (A) Question structure 2 of 2, ABC26OR0959 (B)
(a)eight and eight
(b)eight and sixteen
(c)five and ten
(d)five and eight.
Answer
Answer: D ✓ checked by 4AB · confidence medium

The source book printed C; on checking, D is correct — see the explanation.

Explanation
Pyrene-2,7-diol (D₂h) has five distinct carbons. Pyrene-1,6-diol (C₂h) has eight (d).

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