Q86 · CSIR-NET Chemistry, December 2014

Paper: CSIR-NET December 2014 · Subject: Physical Chemistry · Chapter: Chemical Kinetics · Topic: Rate Laws Order · Marks: 2 · Difficulty: Medium

The rate constant for a reaction $\mathrm{A}^{3+}+\mathrm{B}^{\mathrm{n}+1} \rightarrow \mathrm{P}$ is measured in two different aqueous solutions of ionic strengths 0.01 M and 0.04 M . If $\log \mathrm{K}_{0.04} / \mathrm{K}_{0.01}=0.3$, the charge n on B is closest to
(a)1
(b)2
(c)3
(d)6
Answer
Answer: A ✓ checked by 4AB · confidence high

The source book printed no answer; this one was worked out and checked — see the explanation.

Explanation
log(k/k₀) = 2A z_A z_B √I ⇒ log(k₀.₀₄/k₀.₀₁) = 2 × 0.51 × 3n × (0.2 − 0.1) = 0.306n = 0.3 ⇒ n = 1.

Study loop for Chemical Kinetics

1. Practise the PYQsPrevious-year questions, with answers

· Browse this chapter in the app