Q46 · CSIR-NET Chemistry, December 2018

Paper: CSIR-NET December 2018 · Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Cluster Compounds Wade Rules · Marks: 2 · Difficulty: Easy

Identify the correct statement(s) for $\mathrm{H}_{3}\mathrm{B}.\mathrm{CO}$ (A) $\mathrm{sp}^{2}$ hybridized orbital of B accepts the lone pair of CO. (B) Its $\bar{v}_{\mathrm{CO}}$ value is more than that for free CO (C) Formal oxidation state of C is +4 in the compound Answer is
(a)A and B
(b)B only
(c)A only
(d)A and C
Answer
Answer: B ✓ checked by 4AB · confidence high
Explanation
In H₃B·CO the boron is sp³ (not sp²), ν(CO) (2165 cm⁻¹) is higher than free CO because there is no back-donation, and carbon stays formally +2. Only B is correct.

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