Q12 · CSIR-NET Chemistry, June 2011

Paper: CSIR-NET June 2011 · Subject: Organic Chemistry · Chapter: General Organic Chemistry · Topic: Aromaticity · Marks: 2 · Difficulty: Easy

Among the carbocations given below Question structure 1 of 3, ABC26OR0004 (A) Question structure 2 of 3, ABC26OR0004 (B) Question structure 3 of 3, ABC26OR0004 (C)
(a)A is homoaromatic, B is antiaromatic and C is aromatic.
(b)A is aromatic, B is antiaromatic and C is homoaromatic.
(c)A is antiaromatic, B is aromatic and C is homoaromatic.
(d)A is homoaromatic, B is aromatic and C is antiaromatic.
Answer
Answer: A ✓ checked by 4AB · confidence high
Explanation
A is the homotropylium ion: 6π through the CH₂ bridge, homoaromatic. B, the cyclopentadienyl cation, has 4π and is antiaromatic. C, the cyclopropenyl cation, has 2π and is aromatic (a).

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