Q70 · CSIR-NET Chemistry, June 2015

Paper: CSIR-NET June 2015 · Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Oxidative Addition Reductive Elimination · Marks: 2 · Difficulty: Medium

The least probable product from A on reductive elimination is Question structure, ABC26IN1421 A
(a)Option (a) structure, ABC26IN1421
(b)$\mathrm{CH_4}$
(c)Option (c) structure, ABC26IN1421
(d)Option (d) structure, ABC26IN1421
Answer
Answer: C ✓ checked by 4AB · confidence high
Explanation
From M(n-Pr)(CH₃) one gets butane (direct C–C reductive elimination), CH₄ + propene (β-H elimination, then H–CH₃ elimination) and isobutane (after isomerisation to isopropyl). But-2-ene would need an extra dehydrogenation, so it is least probable (c).

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