Q17 · CSIR-NET Chemistry, June 2018

Paper: CSIR-NET June 2018 · Subject: Organic Chemistry · Chapter: Reagents, Reaction Mechanisms & Named Reactions · Topic: Named Reactions · Marks: 2 · Difficulty: Medium

The major heterocyclic compound formed in the following reaction is Question structure 1 of 7, ABC26OR0373 Question structure 2 of 7, ABC26OR0373 Question structure 3 of 7, ABC26OR0373 Question structure 4 of 7, ABC26OR0373 Question structure 5 of 7, ABC26OR0373 Question structure 6 of 7, ABC26OR0373 Question structure 7 of 7, ABC26OR0373
(a)Option (a) structure, ABC26OR0373
(b)Option (b) structure, ABC26OR0373
(c)Option (c) structure, ABC26OR0373
(d)Option (d) structure, ABC26OR0373
Answer
Answer: C ✓ checked by 4AB · confidence medium
Explanation
N-Boc-pyrrole and ethynyl phenyl sulfone undergo Diels–Alder to the 7-azanorbornadiene. H₂/Pd reduces the unsubstituted, more accessible C=C, leaving the vinyl sulfone (c).

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