The ligand in uranocene is: · ABC26IN0237

Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Organometallic Compounds – General · Exam: CSIR NET 2013 · Marks: 2 · Difficulty: Easy

The ligand in uranocene is:
(a)$\mathrm{C_8H_8^{2-}}$
(b)$\mathrm{C_5H_5^{2-}}$
(c)$\mathrm{C_6H_6}$
(d)$\mathrm{C_4H_4^{2-}}$
Answer
Answer (as printed): A
Explanation
2- The ligand in uranocene is C8H8 35 In the metal-olefin interaction, the extent of increase in metal olefin -back-donation would (a) lead to a decrease in C=C bond length (b) change the formal oxidation state of the metal (c) change the hybridisation of the olefin carbon from sp² to sp³. (d) increase with the presence of electron donating substituent on the olefin. In Metal-Olefin interaction, the extent of increase in metal → Olefin л-back donation would strengthen the Metal-Olefin bond which produces a increase in C = C bond length and somewhat single bond character which results a change in hybridisation from sp² to sp³.

Explanation as extracted from the printed page; notation may be imperfect.

Study loop for Organometallic Compounds

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