ABC26IN1431 · Organometallic Compounds

Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Cluster Compounds Wade Rules · Exam: NET DEC 2015 · Marks: 2 · Difficulty: Hard

Reaction of $\left[\mathrm{Mn}_{2}(\mathrm{CO})_{10}\right]$, with $\mathrm{I}_{2}$, results in A without loss of CO. Compound A, on heating of $120^{\circ} \mathrm{C}$ loses a CO ligand to give B , which does not have a $\mathrm{Mn}-\mathrm{Mn}$ bond. Compound B reacts with pyridine to give 2 equivalents of C . Compounds $\mathrm{A}, \mathrm{B}$ and C from the following respectively, are (I) structure (II) structure (III) structure (IV) structure (V) structure
(a)II, V and IV
(b)II, III and IV
(c)V, III and IV
(d)II, V and III
Answer
Answer (as printed): A
Explanation
No explanation was printed for this question.

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