ABC26PH0388 · Electrochemistry

Subject: Physical Chemistry · Chapter: Electrochemistry · Topic: Electrochemistry – General · Exam: GATE 2005-2021 · Marks: 2 · Difficulty: Medium

For a redox reaction, $\mathrm{Cd}^{2+}+2 \mathrm{e}^{-} \rightleftharpoons \mathrm{Cd}$, the $\left(\mathrm{E}_{\mathrm{p}}\right)_{\text {anodic }}$ observed in cyclic voltametry at hanging mercury drop electrode is -650 mV vs. SCE. The expected value for $\left(\mathrm{E}_{\mathrm{p}}\right)_{\text {cathodic }}$ is
(a)-708 mV
(b)-679 mV
(c)-650 mV
(d)-621 mV
Answer
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Explanation
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