For a 1 molal aqueous NaCl solution, the mean ionic activity coefficient (γ ±)and the Deby-Huckel Limiting… · ABC26PH0395

Subject: Physical Chemistry · Chapter: Electrochemistry · Topic: Electrochemistry – General · Exam: GATE 2005-2021 · Marks: 2 · Difficulty: Medium

For a 1 molal aqueous NaCl solution, the mean ionic activity coefficient $\left(\gamma_{ \pm}\right)$and the Deby-Huckel Limiting Law constant (A) are related as
(a)$\log \gamma_{ \pm}=\sqrt{2} \mathrm{A}$
(b)$\log \gamma_{ \pm}=-\sqrt{2} \mathrm{A}$
(c)$\gamma_{ \pm}=10^{\mathrm{A}}$
(d)$\gamma_{ \pm}=10^{-\mathrm{A}}$
Answer
Answer: D ✓ checked by 4AB · confidence high

The source book printed A; on checking, D is correct — see the explanation.

Explanation
log γ± = −A|z₊z₋|√I. For 1 m NaCl, I = 1, so log γ± = −A and γ± = 10^(−A) (d).

Study loop for Electrochemistry

1. Practise the PYQsPrevious-year questions, with answers

· Browse this chapter in the app